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Moles
The Empirical
Formula from a Reaction.
Example 1.
33·6 g of
iron was found to react with 14·4 g of oxygen.
What is the empirical formula of
iron oxide?
Method.
1) Find how many
moles of iron react with
how many moles of oxygen.
RAM of
Fe = 56, RAM of
O = 16.
moles = mass ÷ RAM
for iron moles = 33·6 ÷
56
=
0·6 moles.
for oxygen moles =
14·4 ÷ 16
=
0·9 moles.
2) The proportion of moles
of iron to moles of oxygen
is reduced to the lowest whole number.
0·6 moles of Fe to 0·9 moles of
O.
Divide by 3, multiply by 10.
2 moles
of Fe to 3
moles of O.
The empirical formula is Fe2O3.
Since
iron oxide is an ionic compound,
the actual formula is the same as the empirical formula.
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